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논문 기본 정보

자료유형
학술저널
저자정보
저널정보
한국식품영양과학회 Journal of Food Science and Nutrition Journal of Food Science and Nutrition Vol.2 No.1
발행연도
1997.3
수록면
1 - 5 (5page)

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Solution properties of polyelectrolytic biopolymers such as chitosan, pectin, alginate and etc. are significantly influenced by molecular weight and salt concentrations. The effect of NaGl concentration on the hydrodynamic properties of chitosan in dilute region was investigated for chitosans of varying molecular weights. Intrinsic viscosity([η]) of chitosans with 5 different molecular weight was determined by glass capillary viscometer, and the viscosity average molecular weight was calculated using Mark-Houwink equation. Intrinsic viscosity decreased with increasing NaGl concentration for all chitosan samples, and it was proportional to the logarithmic NaGl concentration. i.e., [η]∝log (C_(NaCl))^α . Decreasing trend of [η] with NaGl concentration became more pronounced with increasing molecular weight. It was also found that the a values, indicating GNaCl dependence of [η], were linearly correlated with the logarithmic molecular weight(R²=0.980). The chain stiffness parameters (B) were calculated by B=S/([η]_(0.1))^(1.32), in which S was obtained from slope of [η] vs I^(-1/2) The B values of chitosan samples were determined to be 0.113~0.071 with a average of 0.09.

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Abstract

INTRODUCTION

MATERIALS AND METHODS

RESULTS AND DISCUSSION

ACKNOWLEDGEMENTS

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