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대한환경공학회 대한환경공학회지 대한환경공학회지 제16권 제3호
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    초록·키워드

    Highly active Ag/Mn composite catalyst which would oxide dilute carbon monoxide-air mixture formed during anthracite coal combustion at room temperature was prepared. The activity and reaction mechanism of catalyst were investigated which a wide variety of conditions, such as catalyst constituents, flow rate, reaction temperature, reactor size and catalyst pellet size. Based on the optimized results, catalyst was prepared and optimum reactor was constructed, to apply to the actual system.The activity of the MnO₂ catalyst remarkabaly increased by addition of Ag₂O. CO oxidation on Ag₂O/MnO₂ catalyst is first order reaction. The activation energy of CO oxidation in this system is merely 4.53 kcal/mole that is 2~5 times less than CO oxidation catalysts.Oxidation capability of this catalyst was affected by catalyst size but not by reactor size, and was increased with decreasing catalyst pellet size. About 40 % of CO conversion was accomplished by this catalytic reactor in the ambient environment.

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      UCI(KEPA) : I410-ECN-0101-2017-539-001534124