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자료유형
학술저널
저자정보
Muhammad Fahad Khan (COMSATS Institute of Information Technology Pakistan) Sundas Saeed (GC University Lahore Pakistan)
저널정보
한국지질과학협의회 Geosciences Journal Geosciences Journal Vol.22 No.2
발행연도
2018.1
수록면
303 - 312 (10page)

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Mg-calcite (MgCc) is the term used for calcite containing variable magnesium content. The correct determination of the Mg-content in the calcite is of great interest for many fields of research. This study presents the potential, accuracy and the limitations of determining Mg-content in MgCc by means of electron probe micro-analysis (EPMA) coupled with the energy dispersive and wave dispersive spectrometry (EDS/WDS), and X-ray diffractometry (XRD). These techniques were used to examine the distribution of Mg (in mol% MgCO3) in six calcite marble samples from different locations of Peshawar basin (Pakistan), a part of Lesser Himalayas. Results showed variable Mg-content averaging 0.944–1.740 mol% from the chemical analysis with EPMA/EDS of the whole rock sample. This was almost consistent with the XRD findings of 0.750–1.690 mol%. The sample NO13 with heteroblastic grain structure showed disequilibrium geometry due to the contact metamorphism, characterized by the relatively high temperature and low pressure. This caused predominantly quick re-crystallization of the carbonate phase, thus showing lower Mgcontent in the sample. It was assumed that the observed small variability in the Mg-content of the investigated calcites even with in the sample is due to the temperature dependency of the Mg incorporation into the calcites. The highest degree of accuracy in Mg-content determination was observed based on the lattice parameter a and cell volume V. For the Mg-content obtained by XRD, best correlation was observed between the lattice parameter a, cell volume V and Mg-content, with r2 = 0.991 and 0.990 respectively. The difference between the d104 values from the Rietveld refinement and the observed XRD patterns were generally < 0.002 Å.

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