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논문 기본 정보

자료유형
학술저널
저자정보
Yuanyuan Dong (금오공과대학교) Jinho Jang (금오공과대학교)
저널정보
한국염색가공학회 한국염색가공학회지 한국염색가공학회지 Vol. 24 No.2
발행연도
2012.6
수록면
97 - 105 (9page)

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초록· 키워드

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Compared with conventional adsorption-based coloration, the photoreactions of dyes such as photo-copolymerization and photo-crosslinking under UV irradiation can be employed for the coloration of textiles, which can be carried out without salt addition at room temperature. C.I. Reactive Black 5, a homo-bifunctional reactive dye containing two sulfatoethylsulfone groups, is used as a photo-reactive dye for wool fibers. Upon UV irradiation, the photo-reactive dye was grafted onto wool fabrics without photoinitiators. Since the disulfide bonds in the cystine residues of wool can be easily photodecomposed to active thiyl radicals which initiate the polymerization, the dye can be polymerized to an oligomeric dye of a degree of polymerization of 12 or more. The grafted fabrics reached a grafting yield of 2.3% o.w.f. and a color yield (K/S) of 18.2 by the photografting of an aqueous dye concentration of 9% using a UV energy of 25J/㎠. Furthermore, the photochemically dyed wool fabric showed higher colorfastness properties to light, laundering and rubbing comparable to conventional reactive dyeing.

목차

Abstract
1. Introduction
2. Experimental
3. Results and Discussion
4. Conclusions
Acknowledgement
References

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