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논문 기본 정보

자료유형
학술저널
저자정보
Sihao Hua (China Jiliang University) Pengyue Zhang (China Jiliang University) Hangfu Yang (China Jiliang University) Suyin Zhang (China Jiliang University) Hongliang Ge (China Jiliang University)
저널정보
한국자기학회 Journal of Magnetics Journal of Magnetics Vol.18 No.1
발행연도
2013.3
수록면
34 - 38 (5page)

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초록· 키워드

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This paper studies the effects of the Mn-site substitution by nickel on the magnetic properties and the magnetocaloric properties of La<SUB>0.7</SUB>Ca<SUB>0.3</SUB>Mn<SUB>1-x</SUB>Ni<SUB>x</SUB>O₃ (x = 0, 0.05 and 0.1). The orthorhombic crystal structures of the samples are confirmed by the room temperature X-ray diffraction. The dependence of the Curie temperature (T<SUB>C</SUB>) and the magnetic entropy change (ΔS<SUB>M</SUB>) on the Ni doping content was investigated. The samples with x = 0 had the first order phase transition, while the samples with x = 0.05 and 0.1 had the second order phase transition. As the concentration of Ni increased, the maximum entropy change (|ΔS<SUB>M</SUB>|<SUB>max</SUB>) decreased gradually, from 2.78 Jㆍ㎏?¹ㆍK?¹ (x = 0) to 1.02 Jㆍ㎏?¹ㆍK?¹ (x = 0.1), in a magnetic field change of 15 kOe. The measured value of T<SUB>C</SUB> was 185 K, 150 K and 145 K for x = 0, 0.05 and 0.1, respectively. The phase transition temperatures became wider as x increased. It indicates that the Mn-site substitution by Ni may be used to tailor the Curie temperature in La<SUB>0.7</SUB>Ca<SUB>0.3</SUB>Mn<SUB>1-x</SUB>Ni<SUB>x</SUB>O₃.

목차

1. Introduction
2. Experimental
3. Results and Discussion
4. Conclusion
References

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