This study focused on the effect of the biomass blended ratio on air-staged pulverized coal furnace. The hybrid NOx reduction technology between fuel blending and air staging has been applied in an air-staged pulverized coal fired furnace. The results indicated that co-firing biomass with coal could reduce NOx emissions in an air-staged combustion. In addition, carbon burnout and flame temperature increased under the air-staged condition. A dominant synergistic effect on NOx reduction and carbon burnout was observed when biomass co-firing with coal was applied in air staged combustion.