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논문 기본 정보

자료유형
학술대회자료
저자정보
(서울대학교) (서울대학교) (서울대학교) (서울대학교) (삼성전자)
저널정보
대한기계학회 대한기계학회 춘추학술대회 대한기계학회 2018년도 학술대회
발행연도
수록면
227 - 230 (4page)

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초록· 키워드

Fabrication of photoresist (PR) patterning of extreme ultraviolet lithography (EUVL) toward 10 nm highly relies on fundamental understanding of nanoscale heterogeneity in resist matrix. However, currently reported kinetic models are based on homogeneous volume element, and cannot predict EUVL performance variation under heterogeneous resist component distribution such as molecular agglomeration and line edge surface consisting of polymer chains. In this study, we developed multiscale model, density functional theory (DFT)-molecular dynamics (MD)-finite difference method (FDM) integration, reflecting heterogeneous spatial distribution of material ingredients by downscaling the deprotection unit into single pendant group, and it allowed to investigate photo-triggered chemical reaction in molecular level including photo acid generator (PAG) dissociation by secondary electron attachment, acid diffusioncoupled deprotection and solubility switch of individual polymer chain. To quantify deprotection reaction progress, protecting ratio was assigned to pendant group and tracked to distinguish dissoluble PR chains against developer as the process time elapsed. After wiping out the dissoluble chains, morphology of PR line pattern was predicted in sub-10 nm scale from the full description of photo-triggered chemical reaction.
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목차

  1. Abstract
  2. 1. 서론
  3. 2. 방법론
  4. 3. 결과
  5. 4. 결론
  6. 참고문헌

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