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논문 기본 정보

저자정보
(Indian Institute of Technology Roorkee) (Indian Institute of Technology Roorkee) (Indian Institute of Technology Roorkee)
저널정보
대한환경공학회 Environmental Engineering Research Environmental Engineering Research 제24권 제3호
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    초록·키워드

    In this study, iron (Fe) impregnated granular activated carbon (Fe-GAC) has been synthesized and characterized for various properties. Comparative studies have been performed for use of Fe-GAC as an adsorbent as well as a catalyst during catalytic oxidation of hydroquinone (HQ). In the batch adsorption study, effect of process parameter like initial HQ concentration (C₀ = 25-1,000 ㎎/L), pH (2-10), contact time (t: 0-24 h), temperature (T: 15-45℃) and adsorbent dose (w: 5-50 g/L) have been studied. Maximum HQ adsorption efficiency of 75% was obtained at optimum parametric condition of: pH = 4, w = 40 g/L and t = 14 h. Pseudo-second order model best-fitted the HQ adsorption kinetics whereas Langmuir model best-represented the isothermal equilibrium behavior. During oxidation studies, effect of various process parameters like initial HQ concentration (C₀: 20-100 ㎎/L), pH (4-8), oxidant dose (C<SUB>H2O2</SUB>: 0.4-1.6 mL/L) and catalyst dose (m: 0.5-1.5 g/L) have been optimized using Taguchi experimental design matrix. Maximum HQ removal efficiency of 83.56% was obtained at optimum condition of C₀ = 100 ㎎/L, pH = 6, C<SUB>H2O2</SUB> = 0.4 mL/L, and m = 1 g/L. Overall use of Fe-GAC during catalytic oxidation seems to be a better as compared to its use an adsorbent for treatment of HQ bearing wastewater.

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      UCI(KEPA) : I410-ECN-0101-2019-539-000448516