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자료유형
학술저널
저자정보
저널정보
한국원자력학회 Nuclear Engineering and Technology Nuclear Engineering and Technology 제47권 제7호
발행연도
2015.1
수록면
859 - 866 (8page)

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The aim of this work is to investigate the transport mechanism of radioactive nuclidesthrough the reverse osmosis (RO) membrane and to estimate its effectiveness for nuclideseparation from radioactive liquid waste. An analytical model is developed to simulate theRO separation, and a series of experiments are set up to confirm its estimated separationbehavior. The model is based on the extended NernstePlank equation, which handles theconvective flux, diffusive flux, and electromigration flux under electroneutrality and zeroelectric current conditions. The distribution coefficient which arises due to ion interactionswith the membrane material and the electric potential jump at the membrane interface areincluded as boundary conditions in solving the equation. A high Peclet approximation isadopted to simplify the calculation, but the effect of concentration polarization is includedfor a more accurate prediction of separation. Cobalt and cesium are specifically selected forthe experiments in order to check the separation mechanism from liquid waste composedof various radioactive nuclides and nonradioactive substances, and the results arecompared with the estimated cobalt and cesium rejections of the RO membrane using themodel. Experimental and calculated results are shown to be in excellent agreement. Theproposed model will be very useful for the prediction of separation behavior of variousradioactive nuclides by the RO membrane.

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