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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 저널정보
- 한국전기전자재료학회 Transactions on Electrical and Electronic Materials Transactions on Electrical and Electronic Materials 제16권 제3호
- 발행연도
- 2015.1
- 수록면
- 162 - 167 (6page)
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To investigate the effect of fluoro groups substitution on poly(p-phenylenevinylene) derivatives, poly(2,3,5,6- tetrafluoro-p-phenylenevinylene-alt-N-ethylhexyl-3,6-carbazolevinylene), PCTF-PPV, and poly[2,3,5,6-tetrafluorop- phenylenevinylene-alt-2-methoxy-5-(2-ethylhexyloxy)-p-phenylenevinylene], PMTF-PPV, were synthesized by the well-known Wittig condensation polymerization process. To compare the influences of fluoro groups, no fluoro groups containing model polymers, poly(p-phenylenevinylene-alt-N-ethylhexyl-3,6-carbazolevinylene), PCPPPV and poly[p-phenylenevinylene-alt-2-methoxy-5-(2-ethylhexyloxy)-p-phenylenevinylene], p-PMEH-PPV, were also synthesized. The resulting polymers were completely soluble in common organic solvents and exhibited good thermal stability up to 300℃. The polymers showed UV-visible absorbance and photoluminescence (PL) in the ranges of 259~452 nm and 500~580 nm, respectively. The tetrafluorophenyl containing PCTF-PPV and PMTF-PPV showed relatively red-shifted PL peaks at 521 nm and 580 nm, respectively, compared to that of non-fluoro groups containing polymers (PCP-PPV: 500 nm and p-PMEH-PPV: 539 nm). The single-layer light-emitting diode was fabricated in a configuration of ITO/polymer/Al. Electroluminescene (EL) emissions of PCP-PPV, PCTF-PPV, p-PMEH-PPV and PMTF-PPV were shown at 507, 524, 556, and 616 nm, respectively.
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참고문헌 (21)
참고문헌 신청
A. R. Brown / 1992 / Poly(p-phenylenevinylene) light-emitting diodes: Enhanced electroluminescent efficiency through charge carrier confinement / Applied Physics Letters 61
Andrew C. Grimsdale / 1996 / Novel poly(arylene vinylene)s carrying donor and acceptor substituents / Synthetic Metals 76 (1-3) : 165 ~ 167
Andrew C. Grimsdale / 2009 / Synthesis of Light-Emitting Conjugated Polymers for Applications in Electroluminescent Devices / Chemical Reviews 109 (3) : 897 ~ 1091
C. W. Tang / 1987 / Organic electroluminescent diodes / Applied Physics Letters 51 (12) : 913 ~
D. Braun / 1991 / Visible light emission from semiconducting polymer diodes / Applied Physics Letters 58 (18) : 1982 ~
Andrew C. Grimsdale / 1996 / Novel poly(arylene vinylene)s carrying donor and acceptor substituents / Synthetic Metals 76 (1-3) : 165 ~ 167
Andrew C. Grimsdale / 2009 / Synthesis of Light-Emitting Conjugated Polymers for Applications in Electroluminescent Devices / Chemical Reviews 109 (3) : 897 ~ 1091
C. W. Tang / 1987 / Organic electroluminescent diodes / Applied Physics Letters 51 (12) : 913 ~
D. Braun / 1991 / Visible light emission from semiconducting polymer diodes / Applied Physics Letters 58 (18) : 1982 ~
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