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논문 기본 정보

자료유형
학술저널
저자정보
Mekdimu Mezemir Damtie (University of Science & Technology) Federico Volpin (University of Technology) Minwei Yao (University of Technology) Leonard Demegilio Tijing (University of Technology) Ruth Habte Hailemariam (University of Science & Technology) Teng Bao (University of Technology) Kwang-Duck Park (Korea Institute of Civil Engineering and Building Technology) Ho Kyong Shon (University of Technology) June-Seok Choi (University of Science & Technology)
저널정보
대한환경공학회 Environmental Engineering Research Environmental Engineering Research 제26권 제1호
발행연도
2021.2
수록면
67 - 75 (9page)

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초록· 키워드

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The production of the existing nitrogen fertilizer is costly and less environmental-friendly. Various green technologies are currently emerging toward providing alternative options. In this study, a liquid/liquid hydrophobic hollow-fiber membrane contactor was employed at ambient temperature and natural urine pH ~ 9.7 to recover ammonium fertilizers from human urine. Results showed that permeate side chemistry was one of the major factors affecting the ammonia mass transfer. The study on the ammonia capturing performance of diluted sulfuric acid, phosphoric acid, nitric acid, and DI water confirmed that acid type, acid concentration, and permeate side operating pH were the most important parameters affecting the ammonia capturing tendency. Sulfuric acid was slightly better in capturing more ammonia than other acid types. The study also identified increasing acid concentration didn’t necessarily increase ammonia mining tendency because there was always one optimum concentration value at which maximum ammonia extraction was possible. The best permeate side operating pH to extract ammonia for fertilizer purposes was selected based on the dissociation equilibrium of different types of acids. Accordingly, the analysis showed that the membrane process has to be operated at pH > 3 for sulfuric acid, between 3.5 to 11.5 for phosphoric acid, and above 0.5 for nitric acid so as to produce their respective high-quality liquid ammonium sulfate, ammonium monophosphate/diphosphate, and ammonium nitrate fertilizer. Therefore, permeate side acid concentration, pH, and acid type has to always be critically optimized before starting the ammonia mining experiment.

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ABSTRACT
1. Introduction
2. Material and Methods
3. Results and Discussions
4. Conclusions
References

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