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논문 기본 정보

자료유형
학술저널
저자정보
Yoo-Gyum Kang (Korea Atomic Energy Research Institute) Ji-Young Park (Korea Atomic Energy Research Institute) Jong-Myoung Lim (Korea Atomic Energy Research Institute) Mee Jang (Korea Atomic Energy Research Institute) Hyuncheol Kim (Korea Atomic Energy Research Institute) Jin-Hong Lee (Chung-Nam National University)
저널정보
한국분석과학회 분석과학 분석과학 제33권 제4호
발행연도
2020.8
수록면
186 - 196 (11page)

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초록· 키워드

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A simple and rapid preconcentration method of actinide from seawater using Actinide resin was developed and tested with the seawater spiked with a known U and Th. The developed method of Actinide resin based on column chromatography is less time-consuming and requires less labor compared with a typical co-precipitation technique for preconcentration of actinides. U and Th, which are relatively weak-bonded with Actinide resin among actinides, were used to determine the optimum flow rate of seawater sample and evaluate the capacity of Actinide resin to concentrate actinides from seawater. A flow rate of 50 mL min<SUP>-1</SUP> was available with Actinide resin 2 mL (BV, bed volume). When 5 or 10 L of seawater containing U were loaded on Actinide resin (2 mL, BV) at 50 mL min<SUP>-1</SUP>, the recovery of U was 93 % and 86 %, respectively. For extraction of actinides bound with Actinide resin, we compared three methods: solvent extraction, ashing-acid digestion, and ashing-microwave digestion. Ashing-microwave digestion method shows the best performance of which is the recovery of 100 % for U and 81 % for Th. For the preconcentration of actinides in 200 L of seawater, a typical coprecipitation method requires 2-3 days, but the developed method in this study is achieved the high recovery of actinides within 12 h.

목차

Abstract
1. Introduction
2. Materials and Methods
3. Results and Discussion
4. Conclusions
References

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UCI(KEPA) : I410-ECN-0101-2020-433-001079915