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Grafting poly(methacrylic acid) (PMA) onto polyethylene (PE) powders using a photoinitiated reaction with UV irradiation was carried out, and the effects of PMA grafting on the thermal and surface properties of PE were characterized. The PE-g-PMA powders obtained were analyzed by FT-IR spectroscopy, zeta size analysis, thermogravimetric analysis, and differential scanning calorimetry. PE-g-PMA films were prepared by melt pressing the powders and then analyzed by scanning electron microscopy and contact angle measurement. The hydrophilicity of the PE-g-PMA films increased on increasing the degree of grafting. The heat of melt crystallization, heat of melting, melt-crystallization temperature, and melting temperature of PE-g-PMA decreased with increase in the degree of grafting. This was attributed to the PMA chains hindering the crystallization of PE.
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참고문헌 (19)
참고문헌 신청
C. K. Williams / 2008 / Polymers from Renewable Resources; A Perspective for a Special Issue of Polymer Reviews / Polym Rev 48:1~10
A. Razmjou / 2011 / The Effect of Mechanical and Chemical Modification of TiO2 Nanoparticles on the Surface Chemistry, Structure and Fouling Performance of PES Ultrafiltration Membrane / J Membr Sci 378:73~84
V. Svorcik / 2009 / Deposition of Gold Nanoparticles and Nano-layers on Polyethylene Modified by Plasma Discharge and Chemical Treatment / Nucl Instrum Methods Phys Res, Sect B 267:2484~2488
K. Fang / 2008 / Inkjet Printing Effect of Pigment Inks on Silk Fabrics Surface-modified with O2 Plasma / J Appl Polym Sci 107:2949~2955
박병섭 / 2011 / 커플링제 및 점토가 목분/폴리에틸렌 복합체의 물성에 미치는 영향 / 폴리머 35(2):124~129
A. Razmjou / 2011 / The Effect of Mechanical and Chemical Modification of TiO2 Nanoparticles on the Surface Chemistry, Structure and Fouling Performance of PES Ultrafiltration Membrane / J Membr Sci 378:73~84
V. Svorcik / 2009 / Deposition of Gold Nanoparticles and Nano-layers on Polyethylene Modified by Plasma Discharge and Chemical Treatment / Nucl Instrum Methods Phys Res, Sect B 267:2484~2488
K. Fang / 2008 / Inkjet Printing Effect of Pigment Inks on Silk Fabrics Surface-modified with O2 Plasma / J Appl Polym Sci 107:2949~2955
박병섭 / 2011 / 커플링제 및 점토가 목분/폴리에틸렌 복합체의 물성에 미치는 영향 / 폴리머 35(2):124~129
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