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논문 기본 정보

자료유형
학술저널
저자정보
Kim, Tae Yoo (Department of Civil & Environmental Engineering, Pusan National University) Hwang, Kyung-Yup (Suntech Engineering Co., Ltd.) Hwang, Inseong (Department of Civil & Environmental Engineering, Pusan National University)
저널정보
한국지하수토양환경학회 지하수토양환경 지하수토양환경 제21권 제2호
발행연도
2016.1
수록면
29 - 37 (9page)

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CO<sub>2</sub> injection well sealant is vulnerable to supercritical CO<sub>2</sub> (scCO<sub>2</sub>) exposure. To develop an alternative to the conventional sealant system (class G cement/class F fly ash), the performance of slag cement (SPC) systems containing class F fly ash (FFA) or class C fly ash (CFA) was evaluated and compared with the conventional sealant under scCO<sub>2</sub> conditions. All sealant systems showed an immediate increase in compressive strength upon scCO<sub>2</sub> exposure and, at 37.6 MPa, SPC/CFA showed the highest compressive strength after 14 days, which was much higher than the 29.8 MPa of the conventional sealant system. Substantial decreases in porosity were observed in all sealant systems, which were partly responsible for the increase in strength. Carbonation reactions led to pH decreases in the tested sealants from 12.5 to 10~11.6. In particular, the greatest decrease in pH in slag cement/class C fly ash probably supported relatively sustainable alkali activation reactions and the integrity of cement hydrates in this system. XRD revealed the presence of CaCO<sub>3</sub> and a decrease in the content of cement hydrates in the tested sealants upon scCO<sub>2</sub> exposure. TGA demonstrated a greater increase of CaCO<sub>3</sub> and calcium-silicate-hydrate phases in SPC/CFA than in the conventional sealant upon scCO<sub>2</sub> exposure.

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