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The characteristics of aqueous lithium recovery by ion exchange were studied using three commercial cation exchange resins: CMP28 (porous type strong acid exchange resin), SCR-B (gel type strong acid exchange resin) and WK60L (porous type weak acid exchange resin). CMP28 was the most effective material for aqueous lithium recovery; its performance was even enhanced by modifying the cation with $K^+$. A comparison to $Na^+$ and $H^+$ form resins demonstrated that the performance enhancement is reciprocally related to the electronegativity of the cation form. Further kinetic and equilibrium isotherm studies with the $K^+$ form CMP28 showed that aqueous lithium recovery by ion exchange was well fitted with the pseudo-second-order rate equation and the Langmuir isotherm. The maximum ion exchange capacity of aqueous lithium recovery was found to be 14.28 mg/g and the optimal pH was in the region of 4-10.
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참고문헌 (21)
참고문헌 신청
전웅 / 2010 / 리튬 資源 現況 / 자원리싸이클링 19(3):3~8
A. Kitajou / 2003 / Ars Separatoria Acta 2:97
S. Zhu / 2012 / Trans. Nonferrous Met. Soc. China 22:2274
김영상 / 2003 / Chemical Equilibrium and Synergism for Solvent Extraction of Trace Lithium with Thenoyltrifluoroacetone in the Presence of Trioctylphosphine Oxide / Bulletin of the Korean Chemical Society 24(10):1495~1500
F. Wang / 2009 / Trans. Nonferrous Met. Soc. China 19:740
A. Kitajou / 2003 / Ars Separatoria Acta 2:97
S. Zhu / 2012 / Trans. Nonferrous Met. Soc. China 22:2274
김영상 / 2003 / Chemical Equilibrium and Synergism for Solvent Extraction of Trace Lithium with Thenoyltrifluoroacetone in the Presence of Trioctylphosphine Oxide / Bulletin of the Korean Chemical Society 24(10):1495~1500
F. Wang / 2009 / Trans. Nonferrous Met. Soc. China 19:740
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