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(Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University) (Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University) (Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University)
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한국광과학회 Rapid communication in photoscience : RCP Rapid communication in photoscience : RCP 제4권 제1호
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    초록·키워드

    The debromination of phenethyl bromide by the $B_{12}-TiO_2$ hybrid catalyst under UV light irradiation was investigated. The catalytic efficiency was dependent on the type of $TiO_2$. The anatase form of $TiO_2$ was superior to the rutile form of $TiO_2$. The selectivity of the product was also dependent on the crystal structure of $TiO_2$, and the rutile form of $TiO_2$ showed a high selectivity for the formation of the coupling product, 2,3-diphenylbutane, when compared to that of the anatase form of $TiO_2$.

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