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논문 기본 정보

자료유형
학술저널
저자정보
Cui, Mingcan (School of Civil, Environmental and Architecture Engineering, Korea University) Jang, Min (Department of Civil Engineering, Faculty of Engineering, University of Malaya) Kang, Kyounglim (School of Civil, Environmental and Architecture Engineering, Korea University) Kim, Duk Min (Institute of Mine Reclamation Technology Water Treatment Research Team) Kim, Seoungsup (Department of Environmental & Health Suwon Science College) Khim, Jeehyeong (School of Civil, Environmental and Architecture Engineering, Korea University)
저널정보
한국방재학회 한국방재학회논문집 한국방재학회논문집 제13권 제6호
발행연도
2013.1
수록면
401 - 409 (9page)

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The kinetic constant of diethyl phthalate (DEP) oxidized by ultrasound was measured as a function of ultrasound power density, $Cl^-$ concentration and solution temperature. The ultrasonic oxidation kinetic of DEP could be described by the pseudo-first-order reaction d[DEP]/dt = -kCDEP, where k ($min^{-1}$) was identified using Box-Behnken Design coupled with Response Surface Methodology. The final equation for describing the kinetic constant k is as follows: Analysis of variance (ANOVA) tests showed that the second-order polynomial regression model could properly interpret the experimental data with a high determination coefficient ($R^2$, 0.998). The P-value of the model was 0.0001 which is less than 0.05, implying that the model is significant. Besides, the response surface showed that ultrasound power density gave much more effect than another two factors (temperature and $Cl^-$ ion concentration), which provides a possible evidence for the future design.

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