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논문 기본 정보

자료유형
학술저널
저자정보
Maryam Zia (CECOS University) Sulaiman Faisal (CECOS University) Dilawar Farhan Shams (Abdul Wali Khan University) Farida Anjum (Agricultural Research Institute Tarnab) Mehk Saeed (CECOS University) ZiaUllah Shah (CECOS University) Akhtar Nadhman (CECOS University)
저널정보
한국진공학회(ASCT) Applied Science and Convergence Technology Applied Science and Convergence Technology Vol.30 No.3
발행연도
2021.5
수록면
87 - 91 (5page)

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초록· 키워드

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This study investigated the photocatalytic degradation of pure low-density polyethylene (LDPE) and commercial-grade polyethylene (PE) films with iron-doped zinc oxide (Fe-ZnO) nanoparticles under visible light. The study was particularly focused on the role of reactive oxygen species (ROS) and the types of plastic degradation. The Fe-ZnO were synthesized using the co-precipitation method and characterized by TEM and XRD. Degradation of 6.35 cm² films of LDPE and commercial grade PE was tested under artificial LED light (84 lm/W) and dark in Fe-ZnO suspensions of 10 ml having concentrations ranging from 10 to 1000 𝜇g/ml. The results showed a maximum weight reduction of 13.8 % for pure LDPE films at 200 𝜇g/ml and 15 % for commercial grade PE at 1000 𝜇g/ml in 14 days. In comparison, no weight reduction was observed in the dark, which confirmed that the degradation was induced by the production of ROS moieties in visible light i.e., singlet oxygen (30.11 %), hydroxyl ions (30.45 %), and hydroxyl radicals (39.34 %). The degradation was further confirmed by FTIR with the formation of alcohols and alkenes and SEM analysis that showed visible cracks in both LDPE and PE. The study unveiled Fe-ZnO nanoparticles as an efficient substitute to degrade polyethylene under visible light.

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ABSTRACT
1. Introduction
2. Experimental details
3. Results and discussion
4. Conclusions
References

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