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자료유형
학술저널
저자정보
김나은 (한국표준과학연구원) 이혜연 (한국표준과학연구원) 옥수민 (한국표준과학연구원) 송미정 (전북대학교) 이지이 (이화여자대학교) 안준영 (국립환경과학원) 정진상 (한국표준과학연구원)
저널정보
한국대기환경학회 한국대기환경학회지(국문) 한국대기환경학회지 제40권 제3호
발행연도
2024.6
수록면
302 - 318 (17page)
DOI
10.5572/KOSAE.2024.40.3.302

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Nitrous acid (HONO) can produce hydroxyl radical (OH radical) via photolysis during daytime. These OH radicals oxidize volatile organic compounds (VOCs), contributing to the formation of ozone (O₃) and secondary aerosols. In order to investigate the characteristics of HONO in the urban air, HONO and related gaseous compounds were measured in Daejeon, Korea during the winter 2022, and Seoul, Korea during the winter 2020. During the entire measurement period, HONO concentrations were measured to be 0.7±0.6 ppbv and 1.7±1.3 ppbv in Daejeon and Seoul, respectively. HONO showed a very good correlation with nitrogen dioxide (NO₂) with a R2 of 0.78 in Daejeon whereas it showed good correlations with not only NO₂ but also Relative humidity (RH) with R² of 0.8 and 0.62, respectively in Seoul. These results implied that NO₂ is important for the nighttime HONO formation both Daejeon and Seoul during winter while RH is also important in Seoul. It was found that HONO concentrations started to decrease rapidly through photolysis as ultraviolet-A (UV-A) (320~400 nm) intensity increased. The satellite observations showed that high aerosol surface area over the Korean Peninsula during the study period was mainly caused by inflow of the long-range transported haze from the Asian continent. It was found that both high cloud cover and high aerosol surface area decreased UV-A intensity, resulting in less photolysis of HONO. Finally, O₃ was not actively produced due to the decreased UV-A intensity and less photolysis of HONO in Daejeon and Seoul during winter.

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Abstract
1. 서론
2. 연구 방법
3. 결과 및 고찰
4. 결론
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