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논문 기본 정보
- 자료유형
- 학술저널
- 저자정보
- 저널정보
- 한양대학교 청정에너지연구소 Journal of Ceramic Processing Research Journal of Ceramic Processing Research 제8권 제3호
- 발행연도
- 2007.6
- 수록면
- 208 - 212 (5page)
이용수
초록· 키워드
Hybrid glass solid electrolytes are regarded as potential materials for application as electrolytes and separators in secondary
lithium and lithium-ion batteries. Glass electrolyte membranes with nano-channels were prepared by spinodal decomposition
and subsequent acid leaching. The phase-separated, alkali-rich phase was eluted by leaching for 1h at room temperature and
a liquid electrolyte was infiltrated into the 3 dimensionally interconnected channels of the glass membrane to improve of ion
mobility. The most suitable glass electrolyte membranes could be fabricated from 7.5Na2O-46.25B2O3-46.25SiO2 (mol%). The
effects of leaching temperature, leaching time and acid type on the preparation of the membranes were investigated. The
microstructure of the surface and cross-section of 7.5Na2O-46.25B2O3-46.25SiO2 glass electrolytes were examined with a
scanning electron microscope. The channels interconnected throughout the membrane were confirmed to be formed and the
channel size was in the range of 90-200 nm. For electrochemical investigates of the glass electrolyte, full cells were fabricated
using a coin type cell by employing LiCoO2 as a cathode and Mesocarbon Microbeads (MCMB) as an anode.
#hybrid solid electrolyte
#hybrid solid electrolyte
#spinodal decomposition
#spinodal decomposition
#glass electrolyte membrane
#glass electrolyte membrane
#porous glass
#porous glass
#Lithium batteries
#Lithium batteries
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