메뉴 건너뛰기
소속 기관 / 학교 인증
인증하면 논문, 학술자료 등을  무료로 열람할 수 있어요.
한국대학교, 누리자동차, 시립도서관 등 나의 기관을 확인해보세요
(국내 대학 90% 이상 구독 중)
고객센터 ENG
주제분류

논문 기본 정보

저자정보
출처
Springer Science and Business Media LLC Discover Chemical Engineering 3(1)
오류 신고하기
표지

검색

    초록·키워드

    Abstract The attainable region interpretation of the thermodynamic principles has indicated that carbon dioxide (CO 2 ) can be either hydrogenated directly to form dimethyl ether (DME) or gasoline. The process that converts CO 2 to DME is more thermodynamically favourable at lower temperature. A certain thermodynamic temperature range (25 to 300 °C) is suggested for the conversion of CO 2 to DME via a methanol intermediate pathway without addition of work. Optimal synthesis routes derived from P-graph's mutual exclusion solver were compared with reactions reported in literature and showed great correlation. The reactions collectively possess Gibbs free energy of less than zero, and negative enthalpy of reaction. With P-graph attainable region technique, the case studies have demonstrated that the synthesis of DME and gasoline using CO 2 hydrogenation via methanol intermediate and carbon monoxide intermediate from Fischer–Tropsch synthesis is feasible with no work and heat requirement. Both case studies have demonstrated visual advantage of P-graph and data-driven applications. The benefit of integrating the P-graph framework with machine learning model like decision tree classifier was also demonstrated in the second case study as it solves topological optimisation problems without scaling constraints.

    본문·목차

    최근 본 자료 전체보기