인문학
사회과학
자연과학
공학
의약학
농수해양학
예술체육학
복합학
지원사업
학술연구/단체지원/교육 등 연구자 활동을 지속하도록 DBpia가 지원하고 있어요.
커뮤니티
연구자들이 자신의 연구와 전문성을 널리 알리고, 새로운 협력의 기회를 만들 수 있는 네트워킹 공간이에요.
초록·키워드
Despite the rapid progress demonstrated in the efficiency of Perovskite light-emitting diodes (PeLEDs) in the past few years, ion migration has challenged the practical applications of these devices with undesirable hysteresis and degradation effect. Mobile ions in PeLEDs induced many unique and fast transient phenomena occurring on the time scale of microseconds to seconds and it is still far from clear how the underlying physical mechanism of ion motion-induced variation relates to the device performance. Therefore, in this work, we employ an ionic Drift-Diffusion Model (DDM) to evaluate measuring transient current response in a time scale of sub-seconds. The results show that spatial redistribution of ions within the perovskite results in dynamic electric field variation, which in turn, affects charge carrier injection and distribution. Moreover, the time delay between anion and cation migration leads to an unequal rate of charge carrier injection, hence the multi-stage behavior of the current-time response. It is also realized that the potential barrier of charge injection due to cation and anion accumulation at perovskite interfaces with electron and hole transporting layers reduces. Therefore, the facilitation of charge injection favors radiative recombination, and improved IQEs are expected at higher ion densities. It is found that the current-time response of the device gives beneficial information on cation and anion migration time scales. Choosing an appropriate scan rate in accordance with cation-related slow migration time is the first step to achieving reliable measurement procedures and hysteresis-free PeLED.
#Ion
#Microsecond
#Optoelectronics
#Materials science
#Perovskite (structure)
#Diode
#Hysteresis
#Chemical physics
#Charge carrier
#Response time
#Transient (computer programming)
#Light-emitting diode
#Diffusion
#Chemistry
#Computer science
#Physics
#Optics
#Condensed matter physics
#Thermodynamics
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오류를 발견하셨다면 해당 부분을 드래그한 후 ' 를 통해 신고해주세요.
오류를 발견하셨다면 해당 부분을 드래그한 후 ' 를 통해 신고해주세요.