인문학
사회과학
자연과학
공학
의약학
농수해양학
예술체육학
복합학
DBpia AI
AI 에이전트
AI 아이디어
AI 리더
AI 뷰어
Citeasy
크롬 서지관리 다운로드
지원사업
학술연구/단체지원/교육 등 연구자 활동을 지속하도록 DBpia가 지원하고 있어요.
커뮤니티
연구자들이 자신의 연구와 전문성을 널리 알리고, 새로운 협력의 기회를 만들 수 있는 네트워킹 공간이에요.
초록·키워드
Abstract Background Bamboo charcoal has garnered wide recognition as an adsorbent owing to its stability and availability. Phosphoric acid modification contributes to forming specific functional groups on the surface of bamboo charcoal, culminating in the augmentation of its adsorption capabilities. Results The modification process in this study involved impregnating the bamboo charcoal in a 45% mass fraction of phosphoric acid solution with a 1:10 ratio (bamboo charcoal powder to phosphoric acid), followed by activation at a temperature of 500 °C for a duration of 1.5 h. The modification resulted in the formation of hydroxyl, carboxyl, and phosphate groups on the surface of the bamboo charcoal. Furthermore, the specific surface area of the modified bamboo charcoal surged from 4.91 m 2 /g to 115.18 m 2 /g, the average aperture decreased from 7.15 nm to 1.99 nm, and the pore volume escalated by 6.5 times. On this basis, a comparison in the adsorption capability for chlorogenic acid, a natural small-molecule active ingredient, was drawn before and after the modification of bamboo charcoal. The results indicate that the modified bamboo charcoal showcases an impressive 46.8-fold increase in its adsorption capacity when juxtaposed with the unmodified bamboo charcoal. Through the calculations based on density functional theory (DFT), the addition of functional groups on the surface of the modified bamboo charcoal module allows for the formation of hydrogen bonds with the chlorogenic acid module, with the highest binding energy reaching − 57.59 kJ/mol. Conclusion As evidenced by the adsorption kinetic studies, the curve of modified bamboo charcoal for chlorogenic acid abides by a first-order kinetic equation. Additionally, adsorption thermodynamic studies reveal that the curve of modified bamboo charcoal for chlorogenic acid conforms to the Boltzmann equation. These results shed light on the mechanism of selectively adsorbing specific constituents using phosphoric acid-modified bamboo charcoal, thereby providing a solid theoretical foundation for the application of bamboo charcoal. Graphical Abstract
인공지능 문자 인식 모델을 통해 추출된 텍스트로, 일부 오타나 오류가 포함될 수 있으나 지속적으로 개선 중입니다.
오류를 발견하셨다면 해당 부분을 드래그한 후 ' 를 통해 신고해주세요.
오류를 발견하셨다면 해당 부분을 드래그한 후 ' 를 통해 신고해주세요.
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