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커뮤니티
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초록·키워드
We report for the first time a reversible addition-fragmentation chain transfer polymerisation-induced self-assembly (RAFT-PISA) formulation in ionic liquid (IL) that yields worm gels. A series of poly(2-hydroxyethyl methacrylate)-<i>b</i>-poly(benzyl methacrylate) (PHEMA-<i>b</i>-PBzMA) block copolymer nanoparticles were synthesised <i>via</i> RAFT dispersion polymerisation of benzyl methacrylate in the hydrophilic IL 1-ethyl-3-methyl imidazolium dicyanamide, [EMIM][DCA]. This RAFT-PISA formulation can be controlled to afford spherical, worm-like and vesicular nano-objects, with free-standing gels being obtained over a broad range of PBzMA core-forming degrees of polymerisation (DPs). High monomer conversions (≥96%) were obtained within 2 hours for all PISA syntheses as determined by <sup>1</sup>H NMR spectroscopy, and good control over molar mass was confirmed by gel permeation chromatography (GPC). Nanoparticle morphologies were identified using small-angle X-ray scattering (SAXS) and transmission electron microscopy (TEM), and further detailed characterisation was conducted to monitor rheological, electrochemical and thermal characteristics of the nanoparticle dispersions to assess their potential in future electronic applications. Most importantly, this new PISA formulation in IL facilitates the <i>in situ</i> formation of worm ionogel electrolyte materials at copolymer concentrations >4% w/w <i>via</i> efficient and convenient synthesis routes without the need for organic co-solvents or post-polymerisation processing/purification. Moreover, we demonstrate that the worm ionogels developed in this work exhibit comparable electrochemical properties and thermal stability to that of the IL alone, showcasing their potential as gel electrolytes.
#Copolymer
#Materials science
#Methacrylate
#Ionic liquid
#Polymerization
#Raft
#Chain transfer
#Polymer chemistry
#Molar mass
#Monomer
#Chemical engineering
#Small-angle X-ray scattering
#Electrolyte
#Thermal stability
#Nanoparticle
#Dynamic light scattering
#Radical polymerization
#Chemistry
#Organic chemistry
#Nanotechnology
#Electrode
#Polymer
#Scattering
#Physical chemistry
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