인문학
사회과학
자연과학
공학
의약학
농수해양학
예술체육학
복합학
DBpia AI
AI 에이전트
AI 아이디어
AI 리더
AI 뷰어
Citeasy
크롬 서지관리 다운로드
지원사업
학술연구/단체지원/교육 등 연구자 활동을 지속하도록 DBpia가 지원하고 있어요.
커뮤니티
연구자들이 자신의 연구와 전문성을 널리 알리고, 새로운 협력의 기회를 만들 수 있는 네트워킹 공간이에요.
초록·키워드
This research presents a novel approach for the detection of the pesticide chlorpyrifos (CLP) using a gold working electrode immobilized with a graphene oxide-cerium oxide (GO-CeO<sub>2</sub>) nanocomposite in a phosphate buffer (PBS) solution with a pH of 7.0. Graphene oxide (GO) was synthesized <i>via</i> a modified Hummer's method, while cerium oxide (CeO<sub>2</sub>) nanoparticles were prepared using a coprecipitation technique. The GO-CeO<sub>2</sub> nanocomposite was synthesized <i>via</i> sonochemical methods. Structural and morphological characterization of the prepared material was conducted using X-ray diffraction (XRD) and scanning electron microscopy (SEM) coupled with energy dispersive spectroscopy (EDX). Fourier transform infrared (FTIR) spectroscopy has been conducted for the confirmation of functional group presence in the prepared materials. Cyclic voltammetry (CV) was employed to investigate the interaction between the prepared material and the analyte. Further investigations using varying scan rates (5 mV s<sup>-1</sup> to 300 mV s<sup>-1</sup>) revealed a diffusion-controlled process at the electrode-electrolyte interface. Linear sweep voltammetry (LSV) experiments were conducted across a pH range of 5 to 9, with pH 7.0 showing enhanced response for the target pesticides in the presence of the buffer solution. Subsequent electrochemical measurements were performed at pH 7.0. Chronocoulometry was utilized to measure the effective electrode area for electrochemical interactions. Ultrasensitive square wave voltammetry (SWV) was employed for investigating the sensitivity over a concentration range of 1 fM to 100 μM and yielded the limit of detection (LOD) and limit of quantification (LOQ) as 47.7 fM and 159 fM respectively. Interference studies confirmed the selectivity of the prepared sensor, while stability and reproducibility were assessed through controlled experiments. Electrochemical impedance spectroscopy (EIS) was performed to investigate the interactions at the interface. This study provides insights into the development of selective electrochemical sensors for pesticide detection, with potential applications in environmental monitoring.
인공지능 문자 인식 모델을 통해 추출된 텍스트로, 일부 오타나 오류가 포함될 수 있으나 지속적으로 개선 중입니다.
오류를 발견하셨다면 해당 부분을 드래그한 후 ' 를 통해 신고해주세요.
오류를 발견하셨다면 해당 부분을 드래그한 후 ' 를 통해 신고해주세요.
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