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EDP Sciences BIO Web of Conferences 129
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    초록·키워드

    Solid-state batteries are of particular interest when it comes to safe high-energy storage as they potentially enable the usage of lithium anodes.Theoretically, a lithium metal anode has a more than 10 times higher specific charge capacity than graphite [1], which is typically used as anode material in commercially available lithium-ion batteries.But, industrial production of highly reactive lithium metal anodes is challenging.One approach is to electrochemically deposit lithium in a so-called anode-free cell.The lithium is plated between a current collector and the solid electrolyte during charging.In the half-cell assembly investigated throughout this study, the current collector consists of stainless steel and the solid electrolyte of argyrodite-type Li6PS5Cl.The latter is a promising solid electrolyte candidate due to its high ionic conductivity, but comes along with a solid electrolyte interphase (SEI) formation when in contact with lithium metal [2].Therefore, the characterization of interfacial side reactions at the micro-and nanoscale is crucial.

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