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논문 기본 정보

자료유형
학술저널
저자정보
Robert King (The Ohio State University) Hyung Ok Lee (The Ohio State University) David B. Min (The Ohio State University)
저널정보
한국식품과학회 Food Science and Biotechnology Food Science and Biotechnology vol 18. no 2
발행연도
2009.4
수록면
526 - 532 (7page)

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Quenching mechanisms and kinetics of α-, β-, γ-, and δ-tocopherol in photosensitized oxidation of lard were studied. Lard at 0.03, 0.07, 0.11, and 0.3 M in methylene chloride containing 4.4×10?? M chlorophyll and 0, 0.1, 0.3, and 0.6 mM α-, β-, γ-, and δ-tocopherol were stored under light for 4 hr, respectively. Oxidation was determined by headspace oxygen and peroxide value. Tocopherols prevented the photosensitized oxidation of lard (p<0.05). Steady state kinetic study showed that α-, β-, γ-, and δ-tocopherol prevented the photosensitized oxidation of lard by quenching singlet oxygen. Singlet oxygen quenching rates of α-, β-, γ-, and δ-tocopherol by headspace oxygen depletion were 1.86, 2.39, 2.47, and 2.11×10?/M/sec, respectively. The quenching rates of α-, β-, γ-, and δ-tocopherol by peroxide value were 1.42, 1.11, 0.97, and 0.42×10?/M/sec, respectively. The quenching rates of tocopherols were slightly different depending on the measurements of oxidation.

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Abstract
Introduction
Materials and Methods
Results and Discussion
References

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